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In a small saucepan, whisk together the brown sugar, soy sauce, pineapple juice, garlic, pepper, salt, water, and cornstarch.
Bring the brown sugar mixture to a boil and simmer for around 1 to 3 minutes until the mixture just starts to thicken. Remove from heat and reserve 1/4 cup of the sauce for glazing.
Marinate the chicken in the sauce in the fridge for at least 30 minutes.
Thread the chicken on metal skewers along with the peppers and pineapple.
BBQ for 8-10 minutes until the meat is thoroughly cooked. Remove from the barbecue and baste with reserved sauce. Garnish with green onions if desired.